Concentration of the H2 Isotope of Hydrogen by the - download pdf or read online

By Washburn E. W.

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Extra resources for Concentration of the H2 Isotope of Hydrogen by the Fractional Electrolysis of Water

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0 0 H. O. 550 • • • 0 0 0 O. H. O. 5. 0 0 9 > :r w "0 ~ Q> CORROSION 0 /0 "0 Q. 6 ........ 'I'" 2 12 14 .. 0 016 820 0 24 CORROSION 0 2 4 6 8 10 12 14 pH Figure 8. Theoretical and experimental conditions of corrosion, 0, of iron at 25°C. e, and noncorrosion, which causes the form of corrosion known in boiler technology as "caustic cracking" when stresses are present. We have just used the potential-pH equilibrium diagram relating to the system Fe-H2 0 for studying the behavior of iron in the experiments outlined in Figure 1.

The laws of chemical equilibrium, such as the law of mass action of Guldberg and Waage, and the law of solubility productinvolving partial pressures, p (or fugacities, f) and concentrations, c (or activities, a)-do not enable one to study all the equilibria concerned with corrosion. It is necessary to employ the laws of electrochemical equilibrium which include besides pressure, and concentratio:1, an electrode potential. The scale of dissolution potentials emphasized by W. Nernst 9 has been applied to many corrosion studies.

O. 5. 0 0 9 > :r w "0 ~ Q> CORROSION 0 /0 "0 Q. 6 ........ 'I'" 2 12 14 .. 0 016 820 0 24 CORROSION 0 2 4 6 8 10 12 14 pH Figure 8. Theoretical and experimental conditions of corrosion, 0, of iron at 25°C. e, and noncorrosion, which causes the form of corrosion known in boiler technology as "caustic cracking" when stresses are present. We have just used the potential-pH equilibrium diagram relating to the system Fe-H2 0 for studying the behavior of iron in the experiments outlined in Figure 1. 1).

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Concentration of the H2 Isotope of Hydrogen by the Fractional Electrolysis of Water by Washburn E. W.


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