By Tofail Syed;Paul O'Brien;Harold Craighead;Harry Kroto;Halina Podbielska
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Extra info for Biological Interactions with Surface Charge in Biomaterials
In addition, the formation of the charge-transfer surface complex of TiO2 and 2,3-DCP with visible light response contributed to the degradation of 2,3-DCP. 33 Ce–TiO2 samples also exhibit red shifts of the absorption edge and a signiﬁcant enhancement of light absorption at a wavelength of 400–500 nm. 42 Eu31–TiO2 did not show any spectrum absorption in the visible range and only absorbed in the UV range due to the change-transfer process in the bulk TiO2. This means that the catalysts cannot drive the direct photocatalysis under visible light irradiation and Vis/X-3B/Eu31–TiO2 hydrosol system only underwent a sensitized photocatalysis reaction.
B, 1998, 102(52), 10871. 29. S. Malato, P. Ferna´ndez-Iba´n˜ez, M. I. Maldonado, J. Blanco and W. Gernjak, Catal. Today, 2009, 147, 1. 30. F. B. Li, X. Z. Li, M. F. Hou, K. W. Cheah and W. C. H. Choy, Appl. , A, 2005, 285, 181. 31. Y. Zhang, H. Zhang, Y. Xu and Y. Wang, J. , 2004, 177, 3490. 32. F. Han, V. S. R. Kambala, M. Srinivasan, D. Rajarathnam and R. Naidu, Appl. Catal. A, 2009, 359, 25. 33. K. T. Ranjit, I. Willner, S. H. Bossmann and A. M. Braun, Environ. Sci. , 2001, 35, 1544. 34. S. Matsuo, N.
23 This is now termed as vectorial eﬀect and discussed further in Chapter 17. In HA, the polarization is driven by rearrangement of protons at the OH– ions in apatite columnar channels. 24 HA has the potential to store high charge density, which lies within a few tens of nano-Couloumbs to a few milli-Coulombs over a square centimetre area (10À8 –10À3 C cmÀ2). This high charge storage ability is believed to give rise to a signiﬁcantly higher biocompatibility compared to uncharged HA. 3. The HA disk with a diameter of 1 cm and a thickness of 2 mm was polarized in a DC ﬁeld of 2 kV cmÀ1 at 375 1C for 1 h with heating and cooling rate of 5 1C minÀ1.
Biological Interactions with Surface Charge in Biomaterials by Tofail Syed;Paul O'Brien;Harold Craighead;Harry Kroto;Halina Podbielska