Download e-book for kindle: Adsorption on Silica Surfaces by Eugene Papirer

By Eugene Papirer

ISBN-10: 0824700031

ISBN-13: 9780824700034

Presents crucial fabric at the floor and adsorption houses of silica. Progresses from theoretical matters to software, with a historic evaluation, in-depth attention of varied situations of silica adsorption, and effects from fresh learn. Addresses the necessity for particular methods for every kind of silica adsorption and uniquely devotes attention to silica adsorption from resolution. particular themes contain floor chemistry utilizing IR and NMR spectroscopies, desktop modeling, micro- and macromolecular species of adsorbents, and the function of silica debris in section transformation of water. The editor is retired examine director on the Centre nationwide de los angeles Recherche Scientifique, Institut de Chimie des Surfaces et Interfaces, France.

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Chem. 875516 (1983). 72. Chuang, D. Kinney, and G. E. Maciel. J. Am. Chem. 523695 (1993). 73. C. A. Fyfe, G. C. Gobbi, and G. J. Kennedy. J. Phys. Chem. 89:277 (1985). 74. J. A. Carpenter, and J. M. Thomas. J. Chem. Soc. Chem. Comm. 956 (1986). 75. G. Engelhardt and R. Radeglia. Chem. Phys. Lett. 108:271 (1984). Solids 76. R. F. Pettifer, R. Dupree, I. Farnan,andU. Sternberg. 106408 988). 77. LConardelli, L. Facchini, C. Fretigny, P. Tougne, and A. P. Legrand. J. Am. Chem. Soc. 1146412 (1992). (1989).

Bronnimann, R. A. Wind, and G. E. Maciel. J. Magn. Reson. 82:454 (1989). 57. H. Rosenberger, H. Ernst, G. Scheler, I. Junger, and R. Sonnenberger. Z . Phys. Chem. (Leipzig) 263346 (1982). 58. T. Lippmaa, A. V. Samoson, V. Brei, and Yu. I. Gorlov. Dokl. Akad. R. (Phys. ) 259:403 (1981). E. Bronnimann, R. C. Zeigler, and G. E. Maciel. J. Am. Chem. Soc. 110:2023 59. (1988). 60. D. R. 3. Chuang, and G. E. Maciel. J. Am. Cllern. Soc. 115:6786 (1993). 61. C. Liu and G. E. Maciel. J. Am. Chem. Soc. 103 996).

The highly strained four-member site andthereader literature for a discussion [25,26]. is referred to the original can be used to study any nucleus of nonzero spin. In the context of silica es, the nuclei of interest are 'H, "Si, and 1 7 0 . Apart from nuclear abundance, theintensity an NMR signal is determined by the magnetogyric ratio of the nucleus, y, being proportional to its cube. 0025, and it is is by far the easiest nucleus to observe; indeed it is trivially easy with modern instrumentation to obtain the spectrum of 'H in the surface hydroxyl layer of a high-area silica sample.

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Adsorption on Silica Surfaces by Eugene Papirer

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